2004/10/23 | 平衡常数[Equilibrium Constant]
类别(℃〖化学〗) | 评论(0) | 阅读(35) | 发表于 13:24
If , assume complete dissociation and use the charge balance equation. If , solve the equilibrium expression. If , use the exact solution
(1)

To determine the equilibrium constant using a cell consider as an example the equilibrium constant for
(2)

The half-cell equations are
(3)


(4)

From the Nernst equation
(5)

At equilibrium,
(6)

and
(7)

The equilibrium constant of water is
(8)

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