晶体场分裂能[Crystal Field Splitting Energy] - 达人(其实～我是卧底，来自外星)

2004/09/21 | 晶体场分裂能[Crystal Field Splitting Energy]
类别(℃〖化学〗) | 评论(0) | 阅读(46) | 发表于 13:54: The crystal field splitting energy is
(1)

where r is the radius of the orbital and R is the metal-ligand internuclear distance. The crystal splitting energy is altered with pressure, so the position of the peak in an optical absorption spectrum changes with pressure. For octahedral crystals, in order of increasing ,

(2)

For cubic crystals,
(3)

and for tetrahedral crystals,
(4); 0