name |
| system |
temperature |
-quartz (low quartz) | 2.65 |
trigonal |
|
-quartz (high quartz) | 2.53 |
hexagonal |
C |
tridymite |
2.27 |
hexagonal |
C |
cristobalite |
2.33 |
cubic |
C |
coesite |
3.01 |
|
|
stishovite |
4.29 |
octahedral |
|
The transition between and -quartz is displacive, which means that no bonds are broken. It therefore transforms spontaneously to come to equilibrium with its environment. The transformation between -quartz and tridymite is displacive, so bonds are actually broken and reformed. Both tridymite and cristobalite are metastable,
however, and will revert to and -quartz at surface conditions. Coesite is a stable polymorph found in the interior of the earth and at meteor crater. When a small amount of coesite is dissolved in HF, a small residue remains.
This residue contains SiO2 in the rutile structure, i.e., Si in octahedral coordination. Only 3 out of the 3500
surface minerals contain octahedral silicon, two out of three of which are only found in meteorites or impact craters. The
octahedral polymorph of silica is stishovite. A phase diagram of the phases of quartz can be found in Klein and Hurlbut
(1985).