In the rutile structure, the cation is in 6 coordination with the O.  These octahedra form chains, cross-linked by
sharing corners at each cation-O bond.  The central cation as an electrostatic valency of 2/3.
| Mineral | 
Formula | 
| cassierite | 
SnO2 | 
| pyrolusite | 
MnO2 | 
| rutile | 
TiO2 |